The difference between vitrified and sintered

Saturday 18th April 2015

The top fired bar is a translucent porcelain (made from kaolin, silica and feldspar). It has zero porosity and is very hard and strong at room temperature (because fibrous mullite crystals have developed around the quartz and kaolinite grains and feldspar silicate glass has flowed within to cement the matrix together securely). That is what vitrified means. But it has a high fired shrinkage, very poor thermal shock resistance and little stability at above red-heat temperatures. The bar below is zirconium silicate plus 3% binder, all that cements it together is sinter-bonds between closely packed particles (there is no glass development). Yet it is surprisingly strong, it cannot be scratched with metal. It has low fired shrinkage, low thermal expansion and maintains its strength and hardness at very high temperatures.

Pages that reference this post in the Digitalfire Reference Database:

Zircon, Firing: What Happens to Ceramic Ware in a Firing Kiln, Fired Strength, Sinter, sintering, Vitrification, Refractory, Translucency, Primitive Firing

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