How we created a PV Clay substitute

Share from Insight-live.com (Lab Documentation and Calculation System) by Digitalfire. https://digitalfire.com

A recipe of materials that produces a material of similar working and firing properties to Plastic Vitrox


Project Name

PV Clay Substitutes

Project Codenumber

UnAssigned

Notes

PV clay is a plastic feldspar from California, it has long been used in ceramics, mostly at low temperatures to produce white casting bodies. It is also employed in the recipes of many stoneware and even porcelain bodies. And in glazes. However, the manufacturer does not maintain its chemistry, therefore different shipments have different working and firing properties. The difference can be drastic. We chose as a target, the most plastic and vitreous version of PV clay shipments that we have received in the past.

This project is the culmination off many previous attempts to create a duplicate. However this version is the product of a reset to a chemistry match recipe, then adjusting that toward a physical properties match. By "physical properties" we mean plasticity, fired shrinkage, fired porosity, fired color, firing range, etc.

In the coming months we will add a before-and-after physical properties report of an example clay body in which this has been substituted for PV Clay.

PV CLAY Feb 2013 Shipment

Code #

L3664A

Location

BOX35

Materials Amt
PV Clay 100.000

Total:100.00

Auto Unity Formula + Analysis

CaO 0.18 1.00%
MgO 0.13 0.50%
K2O 0.54 5.00%
Na2O 0.15 0.90%
(KNaO) 0.69
TiO2 0.01 0.10%
Al2O3 1.27 12.70%
SiO2 13.01 76.50%
Fe2O3 0.03 0.50%

Ratios

Si:Al: 10.2:1
R2O:RO: 0.7:0.3

Expansion

5.9 (Molar:5.3)

LOI

2.8

Notes

Properties:
Fired shrinkage continues upward until it melts
Hits zero-porosity around cone 4
Moderate plasticity, enough to easily make test bars (if not too soft).
Works well for casting.

Pictures

PV clay bowl at cone 2

L3664A PV sub vs L3894 PV fired bars

PV clay cast bowl at cone 6

Testdata

SHAB - Shrinkage/Absorption

DLEN FLEN FWT BWT CONE DSHR FSHR ABS
595.2485.6439.139.224.84.8%10.1%0.3%
494.7585.3939.4539.534.05.3%9.9%0.2%
395.1686.4440.0641.833.04.8%9.2%4.4%
294.5689.0938.2242.642.05.4%5.8%11.6%
194.6789.7338.9443.511.25.3%5.2%11.7%
695.19curledmelting4.8%

LDW - LOI/Density/Water Content

WWGT DWGT FWGT H2O LOI DENS
122.9217.6217.123.1%3.0%

TSFL - Thermal Shock Failure

CONE SECS MODE MM
364fracture2.9
24.83crack3
132crack3

XML (to paste into Insight)

<?xml version="1.0"?> <recipes version="1.0" encoding="UTF-8"> <recipe name="PV CLAY Feb 2013 Shipment" id="92329" key="RFwxSCu4" date="2021-02-26" codenum="L3664A" location="BOX35" picturebasename=""> <recipelines> <recipeline material="PV Clay" amount="100.000" tolerance=""/> </recipelines> </recipe> </recipes>

Born: 2013-02-27, Modified: 2021-02-26 20:06:31

PV Calc Mix 4

Code #

L3894D

Materials Amt
Silica 25.000
Nepheline Syenite 50.000
Tile #6 Kaolin 20.000
Bentonite 2.500
Dolomite 2.500

Total:100.00

Auto Unity Formula

CaO 0.15
MgO 0.12
K2O 0.17
Na2O 0.56
(KNaO) 0.73
TiO2 0.02
Al2O3 1.34
SiO2 7.58
Fe2O3 0.01

Ratios

Si:Al: 5.7:1
R2O:RO: 0.7:0.3

Expansion

6.8 (Molar:6.5)

LOI

4.5

Notes

Need better plasticity, better maturity. Need to compromise chemistry match to match physical. Switching to NS from custer (for whiteness), more tile6, less silica.

This is about a cone less vitreous than PV clay. But it fires white. Proportions are rounded for production. Plasticity is about the same.

Pictures

L3849D fired bars (cone 02-6 bottom to top)

Testdata

SHAB - Shrinkage/Absorption

DLEN FLEN FWT BWT CONE DSHR FSHR ABS
895.3790.97melting8.04.6%4.6%
795.3288.54melting7.04.7%7.1%
694.4587.4841.4841.746.05.6%7.4%0.6%
595.2787.1141.6841.815.04.7%8.6%0.3%
495.2887.641.9242.934.04.7%8.1%2.4%
395.490.8640.8844.753.04.6%4.8%9.5%
294.8891.6339.7344.782.05.1%3.4%12.7%
195.0592.3739.4245.081.05.0%2.8%14.4%
995.4993.2541.6947.82-1.04.5%2.3%14.7%
1095.8194.139.7146.22-2.04.2%1.8%16.4%

XML (to paste into Insight)

<?xml version="1.0"?> <recipes version="1.0" encoding="UTF-8"> <recipe name="PV Calc Mix 4" id="192685" key="gpe3Y3xK" date="2022-03-09" codenum="L3894D"> <recipelines> <recipeline material="Silica" amount="25.000" tolerance=""/> <recipeline material="Nepheline Syenite" amount="50.000" tolerance=""/> <recipeline material="Tile #6 Kaolin" amount="20.000" tolerance=""/> <recipeline material="Bentonite" amount="2.500" tolerance=""/> <recipeline material="Dolomite" amount="2.500" tolerance=""/> </recipelines> </recipe> </recipes>

Born: 2016-08-12, Modified: 2022-03-09 14:45:51